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【期刊论文】Mathematical Model for Cyclodextrin Alteration of Bioavailability of Organic Pollutants
蔡喜运, Liu Huihui, Cai Xiyun*, Chen Jingwen
Environmental Science & Technology,-0001,():
-1年11月30日
While many cyclodextrin-based applications have been developed to assess or enhance bioavailability of organic pollutants, the choice of cyclodextrin (CD) is largely empirical, with little consideration of pollutant diversity and environmental matrix effects. This study aimed at developing a mathematical model for quantifying CD alteration of bioavailability of organic pollutants. Cyclodextrin appears to have multiple effects, together contributing to its bioavailability-enhancing property. Cyclodextrin is adsorbed onto the adsorbent matrix to different extents. The adsorbed CD is capable of sequestrating organic pollutants, highlighting the role of a pseudophase similar to solid environmental matrix. Aqueous CD can reduce adsorption of organic pollutants via inclusion complexation. The two effects cancel each other to a certain degree, which determines the levels of organic pollutants dissolved (comprising freely dissolved and CD-included forms). Additionally, the CDincluded form is nearly identical in biological activity to the free form. A mathematical model of one variable (i.e., CD concentration) was derived to quantify effects of CD on the bioavailability of organic pollutants. Model analysis indicates that alteration of bioavailability of organic pollutants by CD depends on both CD (type and level) and environmental matrix. The selection of CD type and amendment level for a given application may be predicted by the model.
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蔡喜运, Cai XY, Liu WP, Sheng GY
J. Agric. Food Chem., 2008, 56(6), 2139-2146,-0001,():
-1年11月30日
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蔡喜运, Zhang XX, Wang S, Wang Y, Xia TT, Chen JW, Cai XY*
J. Hazard. Mater., 2011(1), 186, 876-882,-0001,():
-1年11月30日
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蔡喜运, Zhang XX, Xia TT, Chen JW, Huang LP, Cai XY*
J. Agric. Food Chem., 2010, 58(8), 5004-5010,-0001,():
-1年11月30日
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蔡喜运, Bian HT, Chen JW, Cai XY*, Liu P, Liu HH, Qiao XL, Huang LP
J. Agric. Food Chem., 2009, 57(16), 7453-7458,-0001,():
-1年11月30日
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