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2005年05月27日

【期刊论文】纤维素纤维接枝β-环糊精的合成及其富集金属离子研究*

陈文兴, 万军民, 胡智文, 陈文兴**, 陈海相, 余志成

高分子学报,2004,(4):566~572,-0001,():

-1年11月30日

摘要

以环氧氯丙烷作为化学修饰剂,在碱性介质中将β-环糊精接枝到粘胶纤维上,合成了接枝β-环糊精的功能性纤维素纤维,接枝β-环糊精纤维上β-环糊精的含量为7.8%。研究了接枝β-环糊精的纤维素纤维对模拟水样中无机重金属离子的富集性能,考察了温度、浓度、PH值对富集性能的影响。实验结果表明,接枝β-环糊精的纤维素纤维对无机重金属离子(Cu2+、Pd2+、Cd2+)富集效果良好,其富集容量分别达到0.25mmol/g、0.30mmol/g,Cu2+、Pb2+、Cd2+与β-环糊精富集摩尔比分别为2.9: 1、4.3: 1.

β-环糊精,, 环氧氯丙烷,, 功能性纤维,, 无机重金属离子,, 水处理

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2005年05月27日

【期刊论文】Preparation and characterization of noble metal nanocolloids by silk fibroin in situ reduction

陈文兴, CHEN Wenxing, WU Wen, CHEN Haixiang & SHEN Zhiquan

SCIENCE IN CHINA (Series B), August 2003, Vol. 46 No. 4,-0001,():

-1年11月30日

摘要

Noble metal nanocolloids are prepared from their precursors by in situ reduction of a silk fibroin solution at room temperature without any reducing agent. The mechanism, the effects of pH and the molar ratio of the reactants on the reduction reaction are studied by UV-Vis spectroscopy. The structure of the colloids is characterized by FT-IR, TEM and AFM. According to the TEM images, the gold-silk fibroin colloid is a nanostructured bioconjugate with novel core-shell, while the silver-silk fibroin colloid tends to be congregated as clusters having more than ten nanoparticles of silver-silk fibroin. The gold colloid is highly dispersed and stable while the silver colloid is less dispersed and stable than the gold colloid.

silk fibroin,, in situ reduction,, gold colloid,, silver colloid.,

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2005年05月27日

【期刊论文】21世纪的纤维与环境保护

陈文兴, 余志成, 胡智文

纺织学报,2002,23(5):418~420,-0001,():

-1年11月30日

摘要

从纤维的制造、加工及纤维废弃物等方面论述纤维与环境的关系,介绍绿色纤维和绿色加工方面已取得的成就和今后的发展趋势。并指出纤维在主动治理环境污染方面可做出积极的贡献。

纤维 环境保护 绿色纤维 绿色加工 趋势

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2005年05月27日

【期刊论文】Preparation of a novel core-shell nanostructured gold colloid-silk fibroin bioconjugate by the protein in situ redox technique at room temperature†

陈文兴, Yong Zhou, a Wenxing Chen, b Hideaki Itoh, a Kensuke Naka*a Qingqing Ni, b Hideki Yamaneb and Yoshiki Chujo*a

Chem. Commun., 2001, 2518-2519,-0001,():

-1年11月30日

摘要

A novel core-shell gold colloid-silk fibroin (SF) bioconjugate was prepared by the protein in situ redox technique at room temperature, in which the tyrosine (Tyr) residue of the SF, having strong electron donating properties, in situ reduced Au(III) ions to Au colloids showing a stable and highly monodispersed nature.

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2005年05月27日

【期刊论文】A novel air-purifying material based on metallophthalocyanines supported on viscose fibre

陈文兴, Yong Pan, a Wenxing Chen b, * and Yifeng Zhang a

,-0001,():

-1年11月30日

摘要

Two soluble phthalocyanines, cobalt(II)- and iron(III)-octacarboxyphthalocyanines have been examined as catalysts for the oxidation of methanethiol and hydrogen sulphide. Under similar conditions, the cobalt phthalocyanine exhibited higher catalytic activity than the iron compound. On the other hand it was found that when the two catalysts were employed together in equal molar quantities a synergistic effect was observed. For its practical application to the removal of odours caused by methanethiol and hydrogen sulphide, the two metallophthalocyanines were used to dye viscose fibre, pretreated with a cationic agent producing a novel air-purifying material. The dyed fabric was highly effective at eliminating odours caused by these two compounds.

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    浙江理工大学,浙江

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