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2005年04月22日

【期刊论文】Iron-catalysed propylene epoxidation by nitrous oxide: dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

王野， Xiaoxing Wang， Qinghong Zhang， Qian Guo， Yinchuan Lou， L

Chem. Commun., 2004, 1396-1397，-0001，（）：

-1年11月30日

摘要

A dramatic shift of allylic oxidation to epoxidation has been observed during the oxidation of propylene by N2O when the FeOx/SBA-15 catalyst is modified with alkali metal salts, and the roles of alkali metal salts are to suppress the reactivity of lattice oxygen and to induce an iron coordination structure effective for epoxidation with N2O.

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2005年04月22日

【期刊论文】Co2+-Exchanged faujasite zeolites as efficient heterogeneous catalysts for epoxidation of styrene with molecular oxygen

王野， Qinghu Tang， Ye Wang， *， Jun Liang， Ping Wang， Qinghong Zhang， and Huilin Wan

Chem. Commun., 2004, 440-441，-0001，（）：

-1年11月30日

摘要

Co2+-Exchanged faujasite zeolites can efficiently catalyze the epoxidation of styrene with molecular oxygen, and the Co2+ ions located in supercages are suggested to account for the activation of O2 for the epoxidation of styrene.