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施宪法, 毛锋旺, 胡晓钧, 钱洪平, 姚天明,
Acm Phys.-Chim. Sin., 2004, 20 (10): 1271~1274,-0001,():
-1年11月30日
在文献的基础上设计了一套电子/阳离子同向耦合传输的新体系,以多硫l,2二硫醇烯镍的配合物为电子载体、杯芳烃的酯类衍生物为阳离子载体、采用连二亚硫酸钠和铁氰化钾作为还原剂和氧化剂、成功地实现了电子/钾离子同向耦合传输研究了电子载体和离子载体对耦合传输的影响,并对电子耦合传输的传输机理做了初步的研究。
耦合液膜传输,, 杯芳烃衍生物,, [Ni(, dmit), 2] 配合物
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【期刊论文】Synthesis of the tetranitro derivative of thiacalix [4] arene and its acid-base properties
施宪法, Xiaojun Hu, Zhongliang Zhu, Tianxiang Shen, Xianfa Shi, Jie Ren, and Qiuhong Sun
Can. J. Chem. 82: 1266-1270(2004),-0001,():
-1年11月30日
The tetranjuo denivative 3 of thiacalix [4] arene was synthesixed and characterixed. Its aciel-hase water solution were studied by UV spectroscopy. The four pKa walues of 3 were determined by target testi analysis (TTFA). The pure UVabsorqton curves and pH distribution curves of five fornes of 3 presented solution were also caculatied by TTFA.
thiacalixarene, nitro derivative, acid-basc properties
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【期刊论文】Preparation of Calixarene-Containing Polymer with Proton Transport Ability
施宪法, LI WANG, XIANFA SHI, PENGJING JIA, YONG YANG
Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 42, 6259-6266(2004),-0001,():
-1年11月30日
To prepare calixarene-based polymers with proton transport ability, the calix [4] arene derivatives with one polymerizable group at the upper rim were first prepared via selective nitration, amination, and acrylamidation of calix [4] arene. Two methods, solution polymerization and emulsion olymerization, were then employed to carry out the copolymerization of these derivatives with other monomers such as styrene, vinyl acetate, or methyl methacrylate. Transport experiments show that the resulting calixarene-based polymers have a very good ability to transport protons.
polymerizable calixarene derivatives, calixarene-based polymer, proton transport ability
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【期刊论文】杯芳烃的超分子化学研究(IV): 对-叔丁基杯[4]芳烃对ATP的分子识别及液膜传输作用
施宪法, 刘宇a, 陶雅秋a, 曹炎炎a, 梁剑a, 顾金英a, 施宪法*, ①, a, b
化学学报,2002,60(6):1111~1115,-0001,():
-1年11月30日
采用气泡式准乳化液膜法,研究了对-叔丁基杯[4]芳烃对ATP分子的液膜传输作用,讨论了源相与吸收相的组成、酸度、源相中的ATP的起始浓度及吸收相中NH3·H2O 浓度等因素对传输结果的影响;进而讨论了对-叔丁基杯[4] 芳烃对ATP的分子识别作用和液膜传输机理。
杯芳烃, ATP, 分子识别, 液膜传输
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施宪法, Xiaojun Hu a, Ning Xia a, Fei Ye a, Jie Ren b, Xianfa Shi a, c, *
Spectrochimica Acta Part A 60(2004)1427-1430,-0001,():
-1年11月30日
The tetraamino derivative of thiacalix [4] arene (4) was synthesized and characterized. Its acid-base property in water solution was studied by UV spectroscopy. The pH distribution regions of several acidic or basic species of 4 were determined.
Thiacalixarene, Acid-base property
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