-
73浏览
-
0点赞
-
0收藏
-
0分享
-
372下载
-
0评论
-
引用
期刊论文
Thermoresponsive Transport through Porous Membranes with Grafted PNIPAM Gates
April 2003 Vol. 49, No.4,-0001,():
Both thermoresponsive flat membranes and core-shell microcapsule membranes, with (N-isopropylacrylamide) (PNIPAM) a porous membrane substrate and grafted poly N-isopropylacrylamide PNIPAM gates, were successfully prepared using a plasma-graft pore-filling polymerization method. PNIPAM was prepared to be grafted homogeneously onto the porous membrane sub-strates, in the direction of both the membrane thickness and surface. Regardless of the solute molecular size, temperature had an opposite effection diffusion coefficients of the solute across the PNIPAM-grafted membranes with low graft yields as opposed to those with high graft yields. The PE-g-PNIPAM membranes change from positive thermo-response to negative thermoresponse types with increasing pore-filling ratios at around 30%. Phenomenological models were developed for predicting the diffusion coefficient of the solute across PNIPAM-grafted membranes at temperatures, both above and be-low the lower critical solution temperature LCST. Predicted diffusional coefficients of solutes across both the PNIPAM-grafted flat and PNIPAM-grafted microcapsule membranes fit the experimental values. To obtain an ideal result for the diffusional thermoresponsive controlled release through PNIPAM-grafted membranes, the substrates strong enough to prevent any conformation changes are more suitable for preparing thermoresponsive membranes than weak ones.
【免责声明】以下全部内容由[褚良银]上传于[2005年06月30日 19时41分21秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。
本学者其他成果
同领域成果