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期刊论文

Application of the cluster-site approximation (CSA) model to the f.c.c. phase in the Ni-Al system

杜勇F. Zhanga* Y.A. Changb Y.Dub S.-L. Chena W.A. Oatesc

Acta Materialia 51(2003)207-216,-0001,():

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摘要/描述

The modified cluster-site approximation (CSA) model has been used to model the f.c.c. phases (ordered L12 and disordered A1) in the Ni-Al system. The CSA model has the advantage over the cluster variation method (CVM) in that the independent variables in the free energy functional are the site probabilities and not the cluster probabilities. Unlike the zeroth approximation, however, the CSA takes short-range order into consideration, an essential requirement for describing phases that undergo an order/disorder transition, as does the f.c.c. phase in the Ni-Al system. By using the modified CSA model, we have been able to obtain an improved phenomenological description of this system with the use of fewer model parameters than used in previous descriptions. The topology of the calculated metastable f.c.c. phase diagram is similar to the one obtained using a 'first-principles'-CVM approach, whereas the f.c.c. phase diagrams based on the previous phenomenological descriptions are unsatisfactory.

【免责声明】以下全部内容由[杜勇]上传于[2006年09月28日 01时16分38秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

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