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期刊论文

Preparation and Properties of a Salt-Resistant Superabsorbent Polymer

柳明珠Songmei Ma Mingzhu Liu Zhenbin Chen

Journal of Applied Polymer Science, Vol. 93, 2532-2541(2004),-0001,():

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摘要/描述

Crosslinked sodium polyacrylate was prepared by solution polymerization with N,N-methylene-bisacrylamide (bisAM) as crosslinking agent; it was subsequently surface-crosslinked by ethylene glycol diglycidyl ether (EGDE) and then was modified with inorganic salt to obtain a superabsorbent with water absorbency in 0.9 wt % NaCl aqueous solution at atmosphere and applied pressure (P≈2×103Pa) of 55 and 20 g.g-1, respectively. Moreover, it also had excellent hydrogel strength. The effects of reaction temperature, reaction time, neutralization degree (ND) of acrylic acid, amount of initiator, crosslinking agent, and surface-crosslinking agent, mass ratio of inorganic salt to initial superabsorbent, molar ratio of sodium aluminate (NaAlO2) to potassium dihydrogen hyphosphate (KH2PO4) on water absorbency (WA) in 0.9wt % NaCl aqueous, and the hydrogel modulus were investigated and optimized.

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