A self-developed laser image measurement system was established to study the behavior of bubble formation at a single orifice in non-Newtonian Polyacrylamide (PAAm) solutions. The images of bubbles were captured by a CCD camera and the volumes of bubbles were digitally analyzed on-line. The effects of rheological property of PAAm solution, orifice, reservoir and gas flowrate on the bubble formation were studied experimentally. It is found that the bubble volume increases with the concentration of PAAm solution, the diameter of the orifice and the gas flowrate, respectively, whereas little effect by reservoir is observed in experiments.