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期刊论文

Experimental Evidence for the Quantum Confinement Effect in 3C-SiC Nanocry stallites

吴兴龙X. L. Wu* J.Y. Fan T. Qiu X. Yang G. G. Siu and Paul K. Chu

PHYSICAL REVIEW LETTERS 21 JANUARY 2005,-0001,():

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摘要/描述

Using electrochemical etching of a polycrystalline 3C-SiC target and subsequent ultrasonic treatment in water solution, we have fabricated suspensions of 3C-SiC nanocrystallites that luminesce. Transmission electron microscope observations show that the 3C-SiC nanocrystallites, which uniformly disperse in water, have sizes in the range of 1-6nm. Photoluminescence and photoluminescence excitation spectral examinations show clear evidence for the quantum confinement of 3C-SiC nanocrystallites with the emission band maximum ranging from 440 to 560nm. Tunable, composite polystyrene/SiC film can be made by adding polystyrene to a toluene suspension of the 3C-SiC nanocrystallites and then coating the resulting solution onto a Siwafer.

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