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2005年08月19日

【期刊论文】Effect of Atmospheric Plasma Treatment on Desizing of PVA on Cotton

蔡再生, ZAISHENG CAI, AND YIPING QIU, , CHUYANG ZHANG, YOON-JIONG HWANG, AND MARIAN MCCORD

Textile Res. J. 73 (8), 670-674 (2003),-0001,():

-1年11月30日

摘要

Both air/He and air/O2/He atmospheric plasma treatments are applied to desize PVA on cotton, then PDR (percent desizing ratio) and tensile strengths of cotton fabrics and single yams are measured, xPs and SEM are used to analyze the effects of atmospheric pressure plasma treatments on PVA. These treatments can both remove some PVA sizing and significantly improve PDR by washing, especially by cold water washing. The tensile strengths of cotton fabrics treated with atmospheric pressure plasma are the same as for the unsized fabric, xPs analysis of the plasma treated PVA films reveals surface chemical changes such as chain scission and formation of polar groups, which promote the solubility of PVA in Cold water. Air/O2/lIe plasma is more effective than air/lie plasma on PVA desizing.

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2005年08月19日

【期刊论文】IR研究聚氨酯预聚反应的活化能*

蔡再生, 孙铠, 于同隐

功能高分子学报,1995,8(4):475~479,-0001,():

-1年11月30日

摘要

在滴定分析判断聚乙二醇(PEG)和2,4-二甲苯二异氰酸酯(TDI)预聚反应为一级反应的基础上。用IR分析PEG和TDI顸聚反应过程中NCO箕的定量变化,结合Arrhenius经验式求得PEG扣TDI顸聚反应的表表现活化E=86.9kJmol-1。为研完其预聚反应的历程莫定墓础。

IR, 聚乙二醇, 2,, 4-二甲苯二异氰酸酯, 预聚反应

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2005年08月19日

【期刊论文】Chemical finishing of silk fabric

蔡再生, Zaisheng Cai, *, Guochuan Jiang, and Shaojun Yang

Color. Technol., 117 (2001),-0001,():

-1年11月30日

摘要

The optimum technique of finishing silk fabric with EPSIA (a silicone-containing epoxy crosslinking agent) has been investigated through single factor experiments and orthogonal design. Treatment parameters such as finishing agent concentration, catalyst concentration, steaming temperature and time have been investigated. Changes of physical properties, durability to laundering and dyeing properties of the finished silk are also discussed.

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2005年08月19日

【期刊论文】Antimicrobial Finishing of Acrilan Fabrics with Cetylpyridinium Chloride: Affected Properties and Structures

蔡再生, Zaisheng Cai, , Gang Sun

Journal of Applied Polymer Science, Vol. 97, 1227-1236 (2005),-0001,():

-1年11月30日

摘要

Durable antimicrobial acrilan fabrics were prepared by using cetylpyridinium chloride (CPC) in a chemical finishing process. The CPC could form ionic interactions with anionic groups on acrilan fibers, which contribute to durable antimicrobial functions. Reaction conditions such as pH, temperature, and time of the chemical treatment affected exhaustion of CPC and antimicrobial properties. However, the pH conditions of the finishing bath also impacted mechanical properties and color of the fabrics, particularly under alkaline conditions. Although a more alkaline condition is preferred for durable antimicrobial functions, high pH reduces tensile strength and results in yellowing of acrilan fibers. The yellowing of the acrilan fibers is caused by the hydrolysis of acrylonitrle groups and induced formation of conjugated C N systems in the polymers. The conjugated systems were characterized by FTIR.

functionalization of polymers, fibers, FTIR, antimicrobial acrylics, medical textiles

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2005年08月19日

【期刊论文】Antimicrobial Finishing of Acrilan Fabrics with Cetylpyridinium Chloride

蔡再生, Zaisheng Cai, , Gang Sun

Journal of Applied Polymer Science, Vol. 94, 243-247 (2004),-0001,():

-1年11月30日

摘要

Durable antimicrobial properties could be achieved on acrilan fabrics by chemically incorporating biocidal quaternary ammonium salts such as cetylpyridinium chloride (CPC) into the fibers. The chemical interactions between CPC and acrilan fibers were investigated through adsorption isotherm and exhaustion rates of CPC on the fabrics under various conditions. The equilibrium adsorption of CPC on the acrilan fabrics was in good agreement with the Langmuir adsorption isotherm. The study found that CPC concentration, pH value, and finishing temperature and time affected the adsorption process and antimicrobial properties of the acrilan fabrics.

antimicrobial textiles, modification, acrylic fi-bers, functionization of polymers

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    东华大学,上海

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