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2005年08月19日

【期刊论文】Chemical Modification of Bombyx Mori Silk with Epoxide EPSIB

蔡再生, Zaisheng Cai, , Guochuan Jiang, Yiping Qiu

Journal of Applied Polymer Science, Vol. 91, 3579-3586 (2004),-0001,():

-1年11月30日

摘要

Bombyx mori silk fabrics were chemically modified by EPSIB (a multifunctional silicone-containing epoxy crosslinking agent). The reactivity of the epoxy groups with silk fibroin was studied by using amino acid analysis. The physical properties of the modified silks such as resiliency (both wet and dry), moisture regain, dyeing behaviors, and solubility in a mixture solvent (C2H5OH CaCl2: H2O 2: 1: 8, molar ratio) were examined. The modified silk fabrics exhibited a significantly improved resiliency, a small increase in moisture regain and whiteness, and a slightly decreased tensile strength. The contents of Serine, Trosine, Lysine, and Histidine decreased linearly as the wet crease recovery angle (CRA) increased. The solubility in the mixture solvent also decreased as the wet CRA increased. The changes of physical properties, especially the wet CRA, were mainly due to the presence of stable crosslinks between silk fibroin and epoxy groups. The DSC and TGA analyses showed that EPSIB-modified silk fibroin had a higher thermal stability compared with the control.

epoxy resins, modification, proteins, fibroin, silk

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2005年08月19日

【期刊论文】IR研究聚氨酯预聚反应的活化能*

蔡再生, 孙铠, 于同隐

功能高分子学报,1995,8(4):475~479,-0001,():

-1年11月30日

摘要

在滴定分析判断聚乙二醇(PEG)和2,4-二甲苯二异氰酸酯(TDI)预聚反应为一级反应的基础上。用IR分析PEG和TDI顸聚反应过程中NCO箕的定量变化,结合Arrhenius经验式求得PEG扣TDI顸聚反应的表表现活化E=86.9kJmol-1。为研完其预聚反应的历程莫定墓础。

IR, 聚乙二醇, 2,, 4-二甲苯二异氰酸酯, 预聚反应

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2005年08月19日

【期刊论文】三乙撑二胺对聚氨酯预聚反应的催化作用研究确

蔡再生, 陈自力, 孙铠

中国纺织大学学报,1998,24(2):13~16,-0001,():

-1年11月30日

摘要

分析了几种常见的试剂在聚氨酯预聚丘应中的催化活性。在此基础上眚重研完了三乙撑二胺在聚氨醋顸聚反应过程中的催牝机制,井莲过滴定分析和Dsc测试。得出三乙撑二脐之所烈能加快聚氨酯预囊丘应,是固为它能降低反应活化能的结果。

聚氨酯, 三乙撑二胺, 催化作用

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2005年08月19日

【期刊论文】Effect of Atmospheric Plasma Treatment on Desizing of PVA on Cotton

蔡再生, ZAISHENG CAI, AND YIPING QIU, , CHUYANG ZHANG, YOON-JIONG HWANG, AND MARIAN MCCORD

Textile Res. J. 73 (8), 670-674 (2003),-0001,():

-1年11月30日

摘要

Both air/He and air/O2/He atmospheric plasma treatments are applied to desize PVA on cotton, then PDR (percent desizing ratio) and tensile strengths of cotton fabrics and single yams are measured, xPs and SEM are used to analyze the effects of atmospheric pressure plasma treatments on PVA. These treatments can both remove some PVA sizing and significantly improve PDR by washing, especially by cold water washing. The tensile strengths of cotton fabrics treated with atmospheric pressure plasma are the same as for the unsized fabric, xPs analysis of the plasma treated PVA films reveals surface chemical changes such as chain scission and formation of polar groups, which promote the solubility of PVA in Cold water. Air/O2/lIe plasma is more effective than air/lie plasma on PVA desizing.

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2005年08月19日

【期刊论文】含硅环氧树脂的合成及在棉织物上的应用①

蔡再生, 王福爱②, 杨绍军①

有机硅材料及应用,1998(5):5~8,-0001,():

-1年11月30日

摘要

用正交设计方法研究了含硅环氧树脂的合成及其在棉织物上的应用工艺。台成树脂的最佳条件为:中间体2g。含硅化合物10g。环氧氯丙烷8.4g。反应温度70℃,反应时间1h;处理棉府绸最佳工艺为:古硅环氧树脂8%。焙烘温度170℃。焙烘时间4min;处理过的棉其干折皱回复角提高60º以上,湿折皱回复角提高50º以上。

硅, 环氧树脂, 棉织物, 干折皱回复角, 湿折皱回复角

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    东华大学,上海

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