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【期刊论文】Preparation and Characterization of Grafted Collagen-Multiwalled Carbon Nanotubes Composites
周钰明, q
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-1年11月30日
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【期刊论文】Preparation and Proeries of La3+-Loaded Fluorion Adsorbent*
周钰明, Zhou Yuming*, Yu Chumxiang
JOURNAL OF RARE EARTHS, Vol. 22, No.2, Apr. 2004,-0001,():
-1年11月30日
The La3+-loaded adsorbent was prepared by the reaction between La3+ and ethanolamine-modified vegetable tannic extract, to treat Fˉ wree solved. When other conditions were not changed, pH, temperature, stirring time, and dose were changed respectively and the adsorbance was tested respectively. Theresults show that this adsorbent possesses high saturted adsorptive capacity (18.80mg·g-1) when pH is 5~6, T≤80℃, 0.2g dosage, and 180min agitating time, and the adsorbance reaches the highest (98.5). The adsorbent can be easily regenerated with 0.5mol·L-1 NaOH at pH 12.
organic chemistry, adsorbent, adsorption, Fˉ-containing wastewater, rare earths
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周钰明, 单云, 曹勇, , 徐群华, 鞠先, 吴宗汉
高等学校化学学报,2004,25(5):966~970,-0001,():
-1年11月30日
用甲基丙烯酸甲酯在硝酸铈铵和偶氮二异丁腈的联合引发下对胶原进行接枝共聚改性,并用制得的胶原接枝共聚物颗粒与氧化铟纳米粒子复合制成涂层。研究了接枝反应温度及萃取剂对胶原接枝共聚物及其复合物涂层的红外发射率的影响,同时对复合物涂层红外发射率的降低机理进行了初步探讨。结果表明,在反应温度为50~55℃时,先后用丙酮和水作为萃取剂,可制得粒径为40~80nm的胶原接枝共聚物颗粒,该颗粒与氧化铟纳米粒子复合后,涂层的红外发射率(8~14Lm)较单一的胶原接枝共聚物和氧化铟纳米粒子的红外发射率明显降低,胶原接枝共聚物纳米颗粒和氧化铟纳米粒子之间显示出较强的复合协同效应。
胶原, 接枝改性, 红外发射率, 纳米粒子
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【期刊论文】Synthesis of nonlinear optical side-chain soluble polyimides for electro-optic applications
周钰明, W. Z. Leng, Y. M. Zhou*, Q. H. Xu, J. Z. Liu
W. N. Leng et al./Polymer 42(2001)7749-7754,-0001,():
-1年11月30日
Some thermal stable fluorine-containing polymides with side-chain second-order nonlinear optical (NLO) chromophores have been developed, which were prepared by one primidized, hydroxyl polyimide, follwed by the covalent bonding of a chromphore onto the weight percent. Dteailed physical properties showed that the resulting polyimides have good solubility in common organic solvents, relative high glss transition temperatures. Polymer waveguide devices can be easily spin-coated, ensuring a long-term alignment stability at elevated temperatures. These devices exhibit large electro-optic coefficients, 25pm V-1 at 0.83μm, which reained>95% at 120℃ for more than 100h.
Fluorine-containing polyimide, Nonlinear optics, Electro-optic coefficient
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周钰明, Weinan Leng, Yuming Zhou, Qunhua Xu and Juzheng Liu
Polymer Preprints 2001, 42 (2), 372,-0001,():
-1年11月30日
Interest in nonlinear optical (NLO) organic materials has grown tremendously in recent years, primarily because of the telecommunication industry's need for high-bandwidth optical switching and processing devices to serve information and data transmission.1 Recently, a large efforts in chemical research have been aimed at designing and synthesizing novel electrooptical research have been aimed at designing and synthesizing novel electrooptical chromophores with large optical nonlinearities transparency in the near IR.2 However, it is generally recognized that two other performance charcteristics must be achieved in order to ensure the widespread commercial utilization of eletrooptical waveguide modulator technology, Good thermal stability and low optical loss demands that a number of structure-function relationships be defined.3 In this connection, We wish to report bere here our prelimidary results on a prefluorinated polymide system which incorporates three new electrooptical chromophores. These chromophores, based on a nitro group connected with benzothiazole as the acceptor end of donor-π-bridge-acceptor chromophore and a hydroxyl functional amino group as the donor end, have specific chernical stability. With these materials, a novel series of nonlinear optical polyimides can be obtained for optical modulation in waveguide, due to their good solubility, large optical nonlinearity and specific chemical stability.
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