Polyimide (PI)/silica (SiO2) nanohybrid composite waveguide films prepared from Pyromellitic dianhydride (PMDA), 2,2-Bis (3-amino-4-hydroxyphenyl) hexafluoropropane (6FHP), nonlinear optical (NLO) molecule, coupling agent APTES and hydrolysate of TEOS via sol-gel process and thermal imidization. The silicacontent in the hybrid waveguide films varied from 0 to 22.5/wt%. The PI hybrids prepared were characterized by IR, thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM), etc. They exhibit fair good optical transparency. The SiO2 phase is well dispersed in the polymer matrix. DSC and TGA results show that these hybrid waveguide materials have excellent thermal stability.

The La3+-loaded adsorbent was prepared by the reaction between La3+ and ethanolamine-modified vegetable tannic extract, to treat Fˉ wree solved. When other conditions were not changed, pH, temperature, stirring time, and dose were changed respectively and the adsorbance was tested respectively. Theresults show that this adsorbent possesses high saturted adsorptive capacity (18.80mg·g-1) when pH is 5～6, T≤80℃, 0.2g dosage, and 180min agitating time, and the adsorbance reaches the highest (98.5). The adsorbent can be easily regenerated with 0.5mol·L-1 NaOH at pH 12.

用甲基丙烯酸甲酯在硝酸铈铵和偶氮二异丁腈的联合引发下对胶原进行接枝共聚改性，并用制得的胶原接枝共聚物颗粒与氧化铟纳米粒子复合制成涂层。研究了接枝反应温度及萃取剂对胶原接枝共聚物及其复合物涂层的红外发射率的影响，同时对复合物涂层红外发射率的降低机理进行了初步探讨。结果表明，在反应温度为50～55℃时，先后用丙酮和水作为萃取剂，可制得粒径为40～80nm的胶原接枝共聚物颗粒，该颗粒与氧化铟纳米粒子复合后，涂层的红外发射率（8～14Lm）较单一的胶原接枝共聚物和氧化铟纳米粒子的红外发射率明显降低，胶原接枝共聚物纳米颗粒和氧化铟纳米粒子之间显示出较强的复合协同效应。

Some thermal stable fluorine-containing polymides with side-chain second-order nonlinear optical (NLO) chromophores have been developed, which were prepared by one primidized, hydroxyl polyimide, follwed by the covalent bonding of a chromphore onto the weight percent. Dteailed physical properties showed that the resulting polyimides have good solubility in common organic solvents, relative high glss transition temperatures. Polymer waveguide devices can be easily spin-coated, ensuring a long-term alignment stability at elevated temperatures. These devices exhibit large electro-optic coefficients, 25pm V-1 at 0.83μm, which reained>95% at 120℃ for more than 100h.