江焕峰
有机合成,新型催化材料及应用,环境友好合成化学。
个性化签名
- 姓名:江焕峰
- 目前身份:
- 担任导师情况:
- 学位:
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学术头衔:
博士生导师, 国家杰出青年科学基金获得者
- 职称:-
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学科领域:
有机化学
- 研究兴趣:有机合成,新型催化材料及应用,环境友好合成化学。
江焕峰,1993年7月毕业于中国科学院上海有机化学研究所有机化学专业,获理学博士学位。现在华南理工大学化学与化工学院从事科研教学工作,任教授、博士生导师、有机合成化学学术团队负责人、化学与药物化学学科带头人。中国化学会-巴斯夫2001-2002年度“青年知识创新奖”获得者,广东省高等学校“千百十工程”国家级培养对象,2006年度国家杰出青年科学基金获得者,2009年度南粤优秀教师。
长期从事有机合成化学和精细有机化工的应用基础研究与开发工作,主要研究领域包括绿色化学导向的有机合成方法学、新型高效催化剂的设计合成与应用、新型高分子助剂合成及构效关系研究等。
截至2009年9月为止,先后主持国家自然科学基金等课题20多项,在国内外化学领域主流期刊上发表SCI收录研究论文100多篇,论文被SCI收录杂志引用逾200次,EI收录7篇。获得授权中国专利8项。多次参加重要的国际国内学术会议,应邀到一些著名大学及研究机构做学术交流。
主要在研课题:
1.有机合成(国家杰出青年科学基金项目)。项目负责人
2.绿色化学导向的有机反应(国家自然科学基金项目重点项目)。项目负责人
3.过渡金属催化碳碳键形成反应的新合成方法及其应用(国家自然科学基金面上项目)。项目负责人。
研究方向:有机合成,新型催化材料及应用,环境友好合成化学
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219
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成果数
4
江焕峰, Jingmei Huang, Lei Zhou, and Huanfeng Jiang*
Chem. Int. Ed. 2006, 45, 1945-1949,-0001,():
-1年11月30日
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江焕峰, Hua Cao, Xiujun Wang, Huanfeng Jiang*, Qiuhua Zhu, Min Zhang, and Haiyang Liu[a]
Chem. Eur. J. 2008, 14, 11623-11633,-0001,():
-1年11月30日
Based on the reactive bahavour of the substrates, two synthetic routesto polysubstituted pyrimidine derivatives are presented herein: 1) A catalyst-ree multicomponent reaction of electron-deficient alkynes, aliphatic amines and formaldehyde and 2) Ag1- catalyzed synthesis of pyrimidines from electron-deficient alkynes, anilines and formaldehyde by a domino reaction. Under optimized conditions, the multicomponent reactions were accomplished with high regioselectivity and excellent yields. A computational study was carried out by using the B3LYP demsity functional theory to elucidate the mechanisms of the catalyst-free hydroamination reaction. Calculations showed the activation free energies of aliphatic amines were lower than those of anilines, which is consistent with the experimental results.
catalyst-free reactions, density functional calculations, multicomponent reactions, pyrimidines, silver catalyst
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江焕峰, Huanfeng Jiang*, Xiaohang Liu and Lei Zhou[a]
Chem. Eur. J. 2008, 14, 11305-11309,-0001,():
-1年11月30日
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江焕峰, Zhao-Yang Wang a, b, Huan-Feng Jiang*a, Chao-Rong Qi a, Yu-Gang Wang a, Yao-Sen Dong a and Hai-Ling Liu a
Green Chem., 2005, 7, 582-585,-0001,():
-1年11月30日
The Wacker reaction is a good way to produce methyl ketones via the PdII-catalyzed oxidation of terminal olefins.1 In order to improve the activity of the catalyst in the Wacker reaction, many efforts have been made,1 including (1) choice of solvents, such as N,N-dimethylformamide (DMF),2 ethanol,3 acetonitrile (CH3CN),4 and supercritical carbon dioxide (scCO2),5 (2) addition of hexamethylphosphoramide (HMPA),6 (3) substitution for cocatalyst CuCl2 (or CuCl) using benzoquinone (BQ),4 ferric chloide,7 heteropoly acid (HPA),8 ironphthalocyanine (FePc),9 and (4) the supporting of PdII catalyst by polymers.10 Of all the improvements to the PdII-catalyzed Wacker reaction, more and more importance has been attached to the utilization of BQ11 instead of cocatalyst CuCl2 (or CuCl) owing to two other advantages: (1) reducing the quantity of chlorine ion in the reaction solution, which is beneficial to avoid the erosion of metallic reactors and by-products caused by chlorination, and (2) preventing the interference of copper ion in the recovery of precious metal palladium from the remains. Therefore, the substitution of BQ for CuCl2 in the Wacker reaction or similar oxidation of alkenes has been successfully reported by Ba¨ckvall et al.4,12 However, as a small organic molecule, BQ can influence the separation of reaction products and recovery of palladium. If BQ could been fixed on polymer, the process would be simpler. Unfortunately, there have been only a few papers reported on BQ fixed on polymers and its application in the Wacker reaction in a long time.13 Many acetals, such as alkyl 3,3-dialkoxypropanoates, b-ketoacetals and b-cyanoacetal, are important intermediates in organic synthesis and have been used to synthesize a variety of compounds, including coumarins, porphyrins, spermine metabolites, loganin,14 and active cyclic enaminone derivatives, drugs for prevention and treatment of ischemic heart diseases, dyes, pharmaceuticals and auxiliary agents in textile indusrties.15 Of all the methods to prepare these compounds with 3,3-dialkoxy group, the PdII-catalyzed reaction between terminal olefins with electron-withdrawing groups and alcohols as a new type of Wacker reaction is the simplest one.16 In the initial stage, high yield of acetals, such as methyl 3,3-dialkoxypropanoate (92%), must be afforded in DMF and in the presence of expensive and toxic HMPA. Once HMPA was absent, the yield was only 46%.14 As a green reaction solvent, scCO2 has many well-known advantages.5,17 Recently, replacing DMF with scCO2 was realized in the synthesis of methyl 3,3-dimethoxypropanoate according to Hosokawa et al.’s work.16 The result was successful as expected, and the conversion and selectivity was excellent, especially without the non-green reagent HMPA.18 Based on our previous work in scCO2,5,18,19 in this paper we wish to report the studies on application of polymer-supported benzoquinone (PS-BQ) to PdII-catalyzed acetalization of terminal olefins with electron-withdrawing groups in scCO2.
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