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2009年06月26日

【期刊论文】Solubilities of benzene and diphenyl in (t-butyl alcohol Hwater) and hydrophobic interaction

邹立壮， Lizhuang Zou， a， Buxing Han， Ruilin Liu， and Haike Yan b

J. Chem. Thermodynamics 1997, 29, 1289-1299，-0001，（）：

-1年11月30日

The solubilities of benzene and diphenyl in mixed solvents of t-butyl alcohol TBA. and water at Ts298.15, 303.15, 308.15, and 313.15. K have been determined by spectrophotometry. The mole fractions of TBA in the mixed solvent are xs0, 0.010, 0.020, 0.030, 0.040, 0.045, 0.050, 0.060, 0.080, and 0.150., respectively. The standard Gibbs energies of solution of benzene and diphenyl have been calculated based on the solubility data. The hydrophobic interaction HI. for the pair benzene]benzene in the mixed solvent has also been calculated and discussed.

hydrophobic interaction， solubility， benzene， diphenyl,， t-butyl alcohol， water， Gibbs energy

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2009年06月26日

【期刊论文】Hydrophobic interaction of the aggregation of methane and benzene in (water+TBA)

邹立壮， Zou Lizhuang， a， Wang Xiaoling， Zhu Shuquan， Han Buxing， Liu Ruilin， and Yan Haike

J. Chem. Thermodynamics 2002, 34, 1481-1494，-0001，（）：

-1年11月30日

摘要

The solubilities of o-xylene, m-xylene, and p-xylene in mixed solvents of t-butyl alcohol (TBA) and water at T

hydrophobic interaction， solubility， o-xylene， m-xylene， p-xylene， t-butyl alcohol， Gibbs energy

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2009年06月26日

【期刊论文】Enthalpy of Adsorption and Isotherms for Adsorption of Naphthenic Acid onto Clays

邹立壮， Lizhuang Zou，， * Buxing Han， * Haike Yan， *， K. L. Kasperski， † Yuming Xu， † and L. G. Hepler‡

JOURNAL OF COLLOID AND INTERFACE SCIENCE 190, 472-475 (1997)，-0001，（）：

-1年11月30日

摘要

The enthalpies of adsorption and the isotherms for adsorption of naphthenic acid onto Na-montmorillonite, Na-kaolinite, and Na-illite were studied by means of calorimetry and the static method at 298.15 K. The results show that the enthalpies of adsorption and saturated adsorption amounts of naphthenic acid on different clays change in the order Na-montmorillonite ＞Na-illite＞Na-kaolinite. The interaction between naphthenic acid and clays is discussed.

enthalpy of adsorption， adsorption isotherm， naph-thenic acid， clay， enthalpy of dilution

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2009年06月26日

【期刊论文】DECOMPOSITION OF CYCLOHEXYL-t-BUTYL-DIMETHYLAMMONIUM TETRAPHENYLBORATE Synthesis and kinetics

邹立壮， B. Zhou*， S. Jiang**， L. Zou， X. Wang， D. Wan， J. Liu， S. Shang and D. Zhou

Journal of Thermal Analysis and Calorimetry Vol. 58 (1999) 487-493，-0001，（）：

-1年11月30日

摘要

A new compound cyclohexyI-t-butyldimethylammonium tetraphewIborate, [C6H11N(CH3)2(C(CH3)3)]BPh4 has been prepared, and its decomposition mechanism was studied by IG, lhe IR spectra of the products ofthermaI decomposition were examined at every stage, Kinetic analysis for the first stage of thermal decomposition process was obtained by IG and DIG curves, and kinetic parameters were obtained from the analysis of the IG-DTG curyes with integral and differential equations, lhe most pmbable kinetic function was suggested by compari-son of kinetic parameters.

non-isothermal kinetics， quaternary ammonium， tetrapheny Iborate， thennaI decom-position

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2009年06月26日

【期刊论文】TI-W~RMAL DECOMPOSITION OF BARIUM(Ⅱ) TETRAPHENYLBORATE

邹立壮， Zhou Bao-xue， *， Zhong Wet-ke， Zou Li-zhuang and Wang Xiao-ling

Journal of Thermal Analysis, Vol. 47 (1996) 815-820，-0001，（）：

-1年11月30日

摘要

Barium(Ⅱ) tetraphenylborate, Ba(Bph4)2.4H20 was prepared, and its decomposition mechanism was studied by means of TG and DTA. The products of thermal decomposition were examined by means of gas chromatography and chemical methods. A kinetic analysis of the first stage of thermal decomposition was made on the basis of TG and DTG curves and kinetic parameters were obtained from an analysis of the TG and DTG curves using integral and differential methods. The most probable kinetic function was suggested by comparison of kinetic parameters. A mathematical expression was derived for the kinetic compensation effect.

barium(， Ⅱ)， tetraphenylborate， non-isothermal kinetics， thermal decomposition

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