中国科技论文在线

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2011年02月17日

【期刊论文】Synthesis and characterization of polyphosphazenes with sulfur-bearing substituents

王静媛， Hongyang Ma， Yaoxian Li， Hongwen Zhang， Jingyuan Wang*， Feng Li， Xinyi Tang

Materials Chemistry and Physics 73 (2002) 93-96，-0001，（）：

-1年11月30日

A sulfur-bearing substituent, 2-thiazolidinethione, poly (organophosphazene) with side groups of this substituent and its metal polymer complex with cobalt (II) were synthesized and characterized. The structures of these compounds were investigated by means of IR, UV, DTA, EA and 1H NMR. The relationship between the structure and properties of poly (organophosphazene) was discussed. The results show that the poly (organophosphazene) with 2-thiazolidinethione has better thermal stability than the ligand investigated by TGA. Furthermore, the metal polymer complex showed an electroactivity due to the Co2+/Co3+ redox process confirmed by CV.

Polyphosphazenes with sulfur-bearing substituents， Metal polymer complex， Electroactivity

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2011年02月17日

【期刊论文】The synthesis of a new polyorganophosphazene

王静媛， Feng Li， Jingyuan Wang*， Junbo Gao， Xiaoqiang Yu， Jun Tang， Xinyi Tang

Materials Chemistry and Physics 62 (2000) 81-83，-0001，（）：

-1年11月30日

摘要

In this paper, polyorganophosphazene with electroactive property was synthesized by introducing pendant aniline dimer groups. Its structure was characterized by IR and 1H NMR spectrometry. Moreover, its electroactive property and thermal stability were investigated by means of cyclic voltammetry and thermal gravity analysis, respectively. As shown from these results, this polymer not only possesses better thermal stability but also still retains electroactivity.

Polyphosphazene， Aniline dimer， Electroactivity

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2011年02月17日

【期刊论文】三种双功能光折变模型分子的合成及光谱性质研究

王静媛，李峰，孙明昊，李耀先，汤心颐

高等学校化学学报，2001，22（8）：1437～1439，-0001，（）：

-1年11月30日

摘要

The syntheses and spectroscopic properties of three difunctional photorefractivemodelmolecules ethyl [2-cyano-3-(9-ethylcarbazol-3-yl)] acrylate (ECEA), 2-(4-nitrophenyl)-3-(9-ethylcarbazol-3-yl)-acrylonitrile (N PEA) and 9-ethylcarbazol-3-azo-(4-nitrobenzene) (ECAN) are reported in th is paper. The results indicate that the spectroscopic properties are influenced by the structure of three molecules and these molecules belong to p-type sem iconductor.

光折变，咔唑，荧光，光电压