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2005年05月18日

【期刊论文】Self-Assembly of Trigonal-Prismatic Metallocages Encapsulating BF4 or CuI3 2 as Anionic Guests: Structures and Mechanism of Formation**

苏成勇, Cheng-Yong Su, Yue-Peng Cai, Chun-Long Chen, Falk Lissner, Bei-Sheng Kang, * andWolfgang Kaim*

Angew. Chem. Int. Ed. 2002, 41, No.18,-0001,():

-1年11月30日

摘要

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2005年05月18日

【期刊论文】Self-assembly of silver(I) polymers with single strand double-helical structures containing the ligand O,O -bis(8-quinolyl)-1,8-dioxaoctane

苏成勇, Yue-Peng Cai, a b Hua-Xin Zhang, a An-Wu Xu, a Cheng-Yong Su, *a Chun-Long Chen, a Han-Qin Liu, a Li Zhang a and Bei-Sheng Kang *a b

J. Chem. Soc., Dalton Trans., 2001, 2429-2434,-0001,():

-1年11月30日

摘要

The flexible multidentate ligand O,O -bis(8-quinolyl)-1,8-dioxaoctane (ODOQ) reacted with AgX (X = ClO4, BF4, CF3SO3, or CF3CO2) to give four new complexes Ag(ODOQ)]nXn: X=ClO4 1; X=BF4 2; X=CF3SO3 3, and [Ag(ODOQ)(CF3CO2)]n 4. All four complexes have been characterized by elemental analyses, IR and 1H NMR spectroscopy. Single crystal X-ray analyses showed that they have similar 1-D extended architectures with each ligand in "∼"shape, while the chains are alternately and parallelly arranged with the silveratoms as the backbone to form double helical mesomeric strands. The structures are controlled more by the spacer (CH2)6 than by the anions: the versatile coordination geometry of the silver atom is trigonally bonded but changes to distorted tetrahedral or trigonal bipyrimidal via weak AgO interactions. In addition, face-to-face π (in 1-4) and edge-to-face C-Hπ (in 3) interactions as well as hydrogen bonds C-H O and C-H F between adjacent strands assemble the cations in 1-3 or neutral molecules in 4 into an extended network.

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2005年05月18日

【期刊论文】Multidimensional Frameworks Assembled from Silver(I) Coordination Polymers Containing Flexible Bis(thioquinolyl) Ligands: Role of the Intra- and Intermolecular Aromatic Stacking Interactions

苏成勇, Chun-Long Chen, † Cheng-Yong Su, *, † Yue-Peng Cai, † Hua-Xin Zhang, † An-Wu Xu, † Bei-Sheng Kang, †, ‡ and Hans-Conrad zur Loye*, §

Inorganic Chemistry, Vol. 42, No.12, 2003,-0001,():

-1年11月30日

摘要

The two flexible multidentate ligands 1,3-bis(8-thioquinolyl)propane (C3TQ) and 1,4-bis(8-thioquinolyl)butane (C4TQ) were reacted with AgX (X ) CF3SO3 - or ClO4 -) to give four new complexes: {[Ag(C3TQ)](ClO4)}n 1, {[Ag(C3TQ)]- (CF3SO3)}n 2, {[Ag2(C4TQ)(CF3SO3)(CH3CN)](CF3SO3)}n 3, and {[Ag(C4TQ)](ClO4)}n 4. All complexes have been characterized by elemental analysis, IR, and 1H NMR spectroscopy. Single-crystal X-ray analysis showed that chain structures form for all complexes in which the quinoline rings interact via various intra- (1) or intermolecular (2, 3, and 4)

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2005年05月18日

【期刊论文】Luminescent Lanthanide Complexes with Encapsulating Polybenzimidazole Tripodal Ligands

苏成勇, Cheng-Yong Su, † Bei-Sheng Kang, *, † Han-Qin Liu, † Qi-Guang Wang, ‡ Zhong-Ning Chen, † Zhong-Ling Lu, † Ye-Xiang Tong, † and Thomas C. W. Mak*, ‡

Inorganic Chemistry, Vol. 38, No.7, 1999,-0001,():

-1年11月30日

摘要

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2005年05月18日

【期刊论文】Ligand-Directed Molecular Architectures: Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms

苏成勇, Cheng-Yong Su, *, † Yue-Peng Cai, † Chun-Long Chen, † Mark D. Smith, § Wolfgang Kaim, ‡ and Hans-Conrad zur Loye*, §

J. AM. CHEM. SOC. 9 VOL. 125, NO.28, 2003,-0001,():

-1年11月30日

摘要

Three angular ditopic ligands (1,3-bis(benzimidazol-1-ylmethyl)-4,6-dimethylbenzene L1, 1,3- bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene L2, and 1,4-bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene L3) and one tripodal ligand 1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene L4 have been prepared. Reaction of these shape-specific designed ligands with different metal salts affords a series of discrete molecular architectures: [Ag2L1 2](BF4)2 1, [Ag2L2 2](CF3SO3)2 2, [CF3SO3- Ag2L3 2]-CF3SO3 3, [CF3SO3- Ag2L3 3]CF3SO3 4, [ClO4- Cu2L2 4](ClO4)3 5, [4H2O+ Ni2L24Cl4]

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    中山大学,广东

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